Chlorine → HCID 14049251, compound

HRID 2107690Notes

Reaction equation

HRID 2107690 reaction equation
[CH2:1]([Sn:11]([CH2:26][C:27]([C:30]1[CH:35]=[CH:34][CH:33]=[CH:32][CH:31]=1)([CH3:29])[CH3:28])(C1C=CC(F)=CC=1)[C:12]1[CH:17]=[CH:16][C:15]([F:18])=[CH:14][CH:13]=1)[C:2]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)([CH3:4])[CH3:3].[Cl:36]Cl>C(Cl)(Cl)Cl>[CH2:1]([Sn:11]([Cl:36])([CH2:26][C:27]([C:30]1[CH:35]=[CH:34][CH:33]=[CH:32][CH:31]=1)([CH3:29])[CH3:28])[C:12]1[CH:17]=[CH:16][C:15]([F:18])=[CH:14][CH:13]=1)[C:2]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)([CH3:4])[CH3:3]

Participants

4

Reactant 2

HCID 24526ChlorineHCID 14822952HCID 14822952, compound

Product 1

HCID 14049251HCID 14049251, compoundYield 101.3%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

Dineophyl-di(parafluorophenyl)tin (62.1 g, 0.108 mol) prepared above was dissolved in chloroform (200 g). While the resulting solution was maintained at -15° to -20° C., chlorine gas (7.6 g, 0.216 gram atom) was introduced. The mixture was then concentrated under reduced pressure to give 56 g of dineophyl-parafluorophenyltin chloride as a pale-yellow liquid. Gas chromatography analysis indicated 87.5% purity of the desired product.

Workup

  1. temperatureWhile the resulting solution was maintained at -15° to -20° C.
  2. concentrationThe mixture was then concentrated under reduced pressure

Sources & evidence

ORD record
ord-2749672531114e1486efc73112542880
Source dataset
uspto-grants-1990_06
Patent number
US04935408

Reaction notes

Loading…