Methyl iodide → HCID 14852432, compound

HRID 2107733Notes

Reaction equation

[S:1]([C:4]1[NH:5][CH:6]=[C:7]([C:12](=[O:28])[C:13]2[CH:18]=[C:17]([C:19]([CH3:22])([CH3:21])[CH3:20])[C:16]([OH:23])=[C:15]([C:24]([CH3:27])([CH3:26])[CH3:25])[CH:14]=2)[C:8]=1[S:9][C:10]#N)[C:2]#N.CI>>[CH3:2][S:1][C:4]1[NH:5][CH:6]=[C:7]([C:12](=[O:28])[C:13]2[CH:18]=[C:17]([C:19]([CH3:21])([CH3:22])[CH3:20])[C:16]([OH:23])=[C:15]([C:24]([CH3:27])([CH3:26])[CH3:25])[CH:14]=2)[C:8]=1[S:9][CH3:10]

Participants

Reactant 2

HCID 6328Methyl iodide

HCID 14852428HCID 14852428, compound

Product 1

HCID 14852432HCID 14852432, compound

Procedure

For example, using 2,3-dithiocyano-4-(3,5-di-t-butyl-4-hydroxybenzoyl)pyrrole in this general reaction together with two molar equivalents of methyl iodide yields 2,3-dimethylthio-4-(3,5-di-t-butyl-4-hydroxybenzoyl)pyrrole (a compound according to Formula X wherein: m is 0; n is 1; R is H; and Z is H; and X and Y are each SCH3).

Sources & evidence

ORD record: ord-099397dfd4fa4a4cad6cc213271fdef8
Source dataset: uspto-grants-1990_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04935440

Reaction notes

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