2-(1-Dodecyn-1-yl)benzaldehyde → 2-Dodecylbenzaldehyde

HRID 2108068Notes

Reaction equation

HRID 2108068 reaction equation
[C:1]([C:13]1[CH:20]=[CH:19][CH:18]=[CH:17][C:14]=1[CH:15]=[O:16])#[C:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]>[Pd]>[CH2:1]([C:13]1[CH:20]=[CH:19][CH:18]=[CH:17][C:14]=1[CH:15]=[O:16])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

Participants

3

Reactant 1

HCID 197787892-(1-Dodecyn-1-yl)benzaldehyde

Product 1

HCID 140975722-Dodecylbenzaldehyde

Reagents, catalysts & solvents 1

HCID 23938PalladiumCatalyst

Procedure

Alternatively, 2-(1-dodecyn-1-yl)benzaldehyde is hydrogenated in the presence of 10% palladium-on-charcoal (see Example 7b) to give 2-dodecylbenzaldehyde.

Sources & evidence

ORD record
ord-790ab013505143f188e8d3dffe434c9a
Source dataset
uspto-grants-1990_06
Patent number
US04937253

Reaction notes

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