HuagongsheHuagongshe Chemistry Print Report · For research reference only
Aniline → 4-(2-Methyl-4-pyridinyloxy)aniline
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Aniline | HCID 6115 | — |
| Reactant | 1-Butoxy-4-[(4-nitrophenyl)sulfanyl]benzene | HCID 12337965 | — |
| Reactant | 4-[(4-Butoxyphenyl)sulfanyl]aniline | HCID 12337969 | — |
| Reactant | HCID 23023094 | HCID 23023094 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | 4-(2-Methyl-4-pyridinyloxy)aniline | HCID 23023075 | — |
Reaction Steps
4-(4-Butoxyphenyl)thioaniline: 4-(4-Butoxyphenyl)thio-1-nitrobenzene was reduced to the aniline in a manner analagous to that used in the preparation of 3-(trifluoromethyl)-4-(4-pyridinylthio)aniline (Method B3b, Step 2): TLC (33% EtOAc/77% hexane) Rf 0.38. A16. General Method for Synthesis of Substituted Anilines by the Acylation of Diaminoarenes
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07517880B2 |
| Source dataset | uspto-grants-2009_04 |
| ORD ID | ord-5dacecc7768b447187dd34983cce4998 |
| Source note | uspto-grants-2009_04 |