HRID2111498

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：O=S(=O)([O-])C(F)(F)C(F)(F)C(F)(F)C(F)(F)S(=O)(=O)[O-].[K+].[K+]

HCID14384439

未命名化合物

结构：CC(C)(C)c1ccc([S+](c2ccccc2)c2ccccc2)cc1.CC(C)(C)c1ccc([S+](c2ccccc2)c2ccccc2)cc1.[Br-].[Br-]

HCID131727419

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)c1ccc([S+](c2ccccc2)c2ccccc2)cc1.CC(C)(C)c1ccc([S+](c2ccccc2)c2ccccc2)cc1.O=S(=O)([O-])C(F)(F)C(F)(F)C(F)(F)C(F)(F)S(=O)(=O)[O-]

HCID87388164

未命名化合物

PROCEDURE

实验过程

This material was made following Example 1 except perfluorobutane-1,4-disulfonic acid potassium salt and bis(4-t-butylphenyl diphenylsulfonium)bromide were used.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-7c93aac755ca41d1b39b747845a81e8b
来源数据集: uspto-grants-2009_04
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07521170B2
来源说明: uspto-grants-2009_04

反应 SMILES

[K+].[F:2][C:3]([F:21])([S:17]([O-:20])(=[O:19])=[O:18])[C:4]([F:16])([F:15])[C:5]([F:14])([F:13])[C:6]([F:12])([F:11])[S:7]([O-:10])(=[O:9])=[O:8].[K+].[Br-].[C:24]([C:28]1[CH:33]=[CH:32][C:31]([S+:34]([C:41]2[CH:46]=[CH:45][CH:44]=[CH:43][CH:42]=2)[C:35]2[CH:40]=[CH:39][CH:38]=[CH:37][CH:36]=2)=[CH:30][CH:29]=1)([CH3:27])([CH3:26])[CH3:25].[C:47]([C:51]1[CH:56]=[CH:55][C:54]([S+:57]([C:64]2[CH:69]=[CH:68][CH:67]=[CH:66][CH:65]=2)[C:58]2[CH:63]=[CH:62][CH:61]=[CH:60][CH:59]=2)=[CH:53][CH:52]=1)([CH3:50])([CH3:49])[CH3:48].[Br-]>>[F:12][C:6]([F:11])([S:7]([O-:10])(=[O:9])=[O:8])[C:5]([F:14])([F:13])[C:4]([F:15])([F:16])[C:3]([F:2])([F:21])[S:17]([O-:20])(=[O:18])=[O:19].[C:24]([C:28]1[CH:33]=[CH:32][C:31]([S+:34]([C:41]2[CH:46]=[CH:45][CH:44]=[CH:43][CH:42]=2)[C:35]2[CH:36]=[CH:37][CH:38]=[CH:39][CH:40]=2)=[CH:30][CH:29]=1)([CH3:27])([CH3:25])[CH3:26].[C:47]([C:51]1[CH:56]=[CH:55][C:54]([S+:57]([C:64]2[CH:69]=[CH:68][CH:67]=[CH:66][CH:65]=2)[C:58]2[CH:59]=[CH:60][CH:61]=[CH:62][CH:63]=2)=[CH:53][CH:52]=1)([CH3:50])([CH3:48])[CH3:49]