Perfluorobutane-1,4-disulfonic acid potassium salt → Bis(4-t-butylphenyl diphenyl sulfonium) perfluorobutane-1,4-disulfonate

HRID 2111498Notes

Reaction equation

HRID 2111498 reaction equation
[K+].[F:2][C:3]([F:21])([S:17]([O-:20])(=[O:19])=[O:18])[C:4]([F:16])([F:15])[C:5]([F:14])([F:13])[C:6]([F:12])([F:11])[S:7]([O-:10])(=[O:9])=[O:8].[K+].[Br-].[C:24]([C:28]1[CH:33]=[CH:32][C:31]([S+:34]([C:41]2[CH:46]=[CH:45][CH:44]=[CH:43][CH:42]=2)[C:35]2[CH:40]=[CH:39][CH:38]=[CH:37][CH:36]=2)=[CH:30][CH:29]=1)([CH3:27])([CH3:26])[CH3:25].[C:47]([C:51]1[CH:56]=[CH:55][C:54]([S+:57]([C:64]2[CH:69]=[CH:68][CH:67]=[CH:66][CH:65]=2)[C:58]2[CH:63]=[CH:62][CH:61]=[CH:60][CH:59]=2)=[CH:53][CH:52]=1)([CH3:50])([CH3:49])[CH3:48].[Br-]>>[F:12][C:6]([F:11])([S:7]([O-:10])(=[O:9])=[O:8])[C:5]([F:14])([F:13])[C:4]([F:15])([F:16])[C:3]([F:2])([F:21])[S:17]([O-:20])(=[O:18])=[O:19].[C:24]([C:28]1[CH:33]=[CH:32][C:31]([S+:34]([C:41]2[CH:46]=[CH:45][CH:44]=[CH:43][CH:42]=2)[C:35]2[CH:36]=[CH:37][CH:38]=[CH:39][CH:40]=2)=[CH:30][CH:29]=1)([CH3:27])([CH3:25])[CH3:26].[C:47]([C:51]1[CH:56]=[CH:55][C:54]([S+:57]([C:64]2[CH:69]=[CH:68][CH:67]=[CH:66][CH:65]=2)[C:58]2[CH:59]=[CH:60][CH:61]=[CH:62][CH:63]=2)=[CH:53][CH:52]=1)([CH3:50])([CH3:48])[CH3:49]

Participants

3

Reactant 2

HCID 14384439Perfluorobutane-1,4-disulfonic acid potassium saltHCID 131727419Bis(4-t-butylphenyl diphenylsulfonium)bromide

Product 1

HCID 87388164Bis(4-t-butylphenyl diphenyl sulfonium) perfluorobutane-1,4-disulfonate

Procedure

This material was made following Example 1 except perfluorobutane-1,4-disulfonic acid potassium salt and bis(4-t-butylphenyl diphenylsulfonium)bromide were used.

Sources & evidence

ORD record
ord-7c93aac755ca41d1b39b747845a81e8b
Source dataset
uspto-grants-2009_04
Patent number
US07521170B2

Reaction notes

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