HuagongsheHuagongshe Chemistry Print Report · For research reference only
(3-Bromo-4-chlorophenyl)methanol → 3-Bromo-4-chlorobenzaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (3-Bromo-4-chlorophenyl)methanol | HCID 50998689 | — |
| Catalyst | Manganese dioxide | HCID 14801 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | 3-Bromo-4-chlorobenzaldehyde | HCID 14049809 | 62.4% |
Reaction Steps
A solution of 3-bromo-4-chlorobenzyl alcohol (3.24 g, 14.6 mmol) in acetone (100 mL) was treated with MnO2 (16.2 g, 73 mmol) and the mixture stirred for 3 days then filtered over diatomaceous earth. The filtrate was concentrated under reduced pressure to afford 2.0 g of title compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07524873B2 |
| Source dataset | uspto-grants-2009_04 |
| ORD ID | ord-7b08a386df9a4220ae45b24098547fa0 |
| Source note | uspto-grants-2009_04 |