HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2113150Generated: November 1, 2026
Ethyl Acetate → 1-[(Prop-2-en-1-yl)oxy]-4-[(trifluoromethyl)sulfanyl]benzene
https://huagongshe.com/reaction/2113150
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Ethyl Acetate | HCID 8857 | — |
| Reactant | Cesium carbonate | HCID 10796 | — |
| Reactant | 4-(Trifluoromethylsulfanyl)phenol | HCID 3815158 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 1-[(Prop-2-en-1-yl)oxy]-4-[(trifluoromethyl)sulfanyl]benzene | HCID 69050030 | — |
Reaction Steps
A mixture of 4-(trifluoromethylsulfanyl)phenol (1.9 g, 10 mmol), allyl brimide (1.8 g, 15 mmol) and Cs2CO3 (6.5 g, 20 mmol) in DMF, 80 mL) was stirred for 2 hrs at 50° C. The reaction was diluted with ethyl acetate and washed with water. The organic phase was dried and concentrated to give essentially pure allyl 4-(trifluoromethylsulfanyl)phenyl ether.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US07524882B2 |
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| Source dataset | uspto-grants-2009_04 |
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| ORD ID | ord-3f5b31533c4140eb8dcadd2d494bf0fc |
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| Source note | uspto-grants-2009_04 |
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