HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,4-Dibromobenzene → 1,4-Didecylbenzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,4-Dibromobenzene | HCID 7804 | — |
| Reactant | HCID 178418384 | HCID 178418384 | — |
| Catalyst | Bis(cyclopenta-1,4-dien-1-yl(diphenyl)phosphane);dichloropalladium;iron(2+) | HCID 178418228 | — |
| Product | 1,4-Didecylbenzene | HCID 296269 | — |
| Product | 1,4-Dibromo-2,5-didecylbenzene | HCID 23072555 | — |
Reaction Steps
2,5-Dibromo-1,4-didecylbenzene is prepared from 1,4-dibromobenzene in two steps according to literature procedures: decylmagnesium bromide is coupled to 1,4 dibromobenzene using PdCl2(dppf) to yield 1,4-didecylbenzene, which is subsequently treated with bromine to afford 2,5-dibromo-1,4-didecylbenzene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07524922B2 |
| Source dataset | uspto-grants-2009_04 |
| ORD ID | ord-c64b8e42f6ef485c8b5aca88784917f4 |
| Source note | uspto-grants-2009_04 |