HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,5-Dibromopyridine → 2,5-Bis(methylthio)pyridine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,5-Dibromopyridine | HCID 69353 | — |
| Reactant | Sodium methanethiolate | HCID 4378561 | — |
| Reactant | 2,5-Bis(methylsulfonyl)pyridine | HCID 13102675 | — |
| Product | 2,5-Bis(methylthio)pyridine | HCID 12269210 | — |
Reaction Steps
The 2,5-bismethanesulfonylpyridine was obtained by reacting 2,5-dibromopyridine with sodium thiomethoxide to obtain 2,5-bis-methylthiopyridine, and then oxidizing it with metachloroperbenzoic acid. The reaction between 2,5-dibromopyridine and sodium methoxide and the oxidation of 2,5-bis-methylthiopyridine with metachloroperbenzoic acid may be carried out according to ordinary methods.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07432287B2 |
| Source dataset | uspto-grants-2008_10 |
| ORD ID | ord-4875ac8b14674b978bbc001b9ce62bac |
| Source note | uspto-grants-2008_10 |