Tetrafluoro-m-phenylenediamine dihydrochloride → HCID 69254665, compound

HRID 2114525Notes

Reaction equation

HRID 2114525 reaction equation
[CH:1]([O:4][CH2:5][CH2:6][NH:7][C:8]1[CH:13]=[CH:12][C:11]([N+:14]([O-])=O)=[CH:10][CH:9]=1)([CH3:3])[CH3:2].C1(N)C(F)=C(F)C(F)=C(N)C=1F.[ClH:29].Cl>[Zn].[Cl-].[NH4+].O.C(O)C>[ClH:29].[ClH:29].[CH:1]([O:4][CH2:5][CH2:6][NH:7][C:8]1[CH:9]=[CH:10][C:11]([NH2:14])=[CH:12][CH:13]=1)([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 149026Tetrafluoro-m-phenylenediamine dihydrochlorideHCID 23104380HCID 23104380, compound

Product 1

HCID 69254665HCID 69254665, compound

Reagents, catalysts & solvents 1

HCID 131726756ZINC ammonium chloride water ethanolCatalyst

Procedure

The N-(2-isopropoxyethyl)-4-nitro-1-aminobenzene (7) obtained above was reduced with a boiling zinc/ammonium chloride/water/ethanol mixture. The corresponding amine was isolated in dihydrochloride form.

Sources & evidence

ORD record
ord-4b46e5de0a0f4a98b12aadaacd8ed81f
Source dataset
uspto-grants-2008_10
Patent number
US07435267B2

Reaction notes

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