HCID 58596125, compound → HCID 58596112, compound

HRID 2114527Notes

Reaction equation

HRID 2114527 reaction equation
[CH2:1]([CH:3]([CH2:19][CH2:20][CH2:21][CH3:22])[CH2:4][O:5][CH2:6][CH2:7][CH2:8][NH:9][C:10]1[CH:15]=[CH:14][C:13]([N+:16]([O-])=O)=[CH:12][CH:11]=1)[CH3:2]>C1(N)C(F)=C(F)C(F)=C(N)C=1F.Cl.Cl.[Zn].[Cl-].[NH4+].O.C(O)C>[CH2:1]([CH:3]([CH2:19][CH2:20][CH2:21][CH3:22])[CH2:4][O:5][CH2:6][CH2:7][CH2:8][NH:9][C:10]1[CH:11]=[CH:12][C:13]([NH2:16])=[CH:14][CH:15]=1)[CH3:2]

Participants

4

Reactant 1

HCID 58596125HCID 58596125, compound

Product 1

HCID 58596112HCID 58596112, compound

Reagents, catalysts & solvents 2

HCID 131726756ZINC ammonium chloride water ethanolCatalystHCID 149026Tetrafluoro-m-phenylenediamine dihydrochlorideSolvent

Procedure

The N-[2-(3-ethylheptyloxy)ethyl]-4-nitro-1-aminobenzene (9) obtained above was reduced with a boiling zinc/ammonium chloride/water/ethanol mixture. The corresponding amine was isolated in dihydrochloride form.

Sources & evidence

ORD record
ord-0a0c48b36f284cf88b7bec275a234ece
Source dataset
uspto-grants-2008_10
Patent number
US07435267B2

Reaction notes

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