Tetrafluoro-m-phenylenediamine dihydrochloride → HCID 69255077, compound

HRID 2114528Notes

Reaction equation

HRID 2114528 reaction equation
[CH:1]([O:4][CH2:5][CH2:6][CH2:7][NH:8][C:9]1[CH:14]=[CH:13][C:12]([N+:15]([O-])=O)=[CH:11][C:10]=1[O:18][CH3:19])([CH3:3])[CH3:2].C1(N)C(F)=C(F)C(F)=C(N)C=1F.[ClH:32].Cl>[Zn].[Cl-].[NH4+].O.C(O)C>[ClH:32].[ClH:32].[NH2:15][C:12]1[CH:13]=[CH:14][C:9]([NH:8][CH2:7][CH2:6][CH2:5][O:4][CH:1]([CH3:3])[CH3:2])=[C:10]([O:18][CH3:19])[CH:11]=1

Participants

4

Reactant 2

HCID 149026Tetrafluoro-m-phenylenediamine dihydrochlorideHCID 23104359HCID 23104359, compound

Product 1

HCID 69255077HCID 69255077, compound

Reagents, catalysts & solvents 1

HCID 131726756ZINC ammonium chloride water ethanolCatalyst

Procedure

The N-(3-isopropoxypropyl)-N-(2-methoxy-4-nitrophenyl)amine (11) obtained above was reduced with a boiling zinc/ammonium chloride/water/ethanol mixture. The corresponding amine was isolated in dihydrochloride form.

Sources & evidence

ORD record
ord-abfe7fcfb9e44ad79739ac2fba207d1d
Source dataset
uspto-grants-2008_10
Patent number
US07435267B2

Reaction notes

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