Tetrafluoro-m-phenylenediamine dihydrochloride → HCID 23104355, compound

HRID 2114530Notes

Reaction equation

HRID 2114530 reaction equation
[CH3:1][O:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][NH:9][C:10]1[CH:15]=[CH:14][C:13]([N+:16]([O-])=O)=[CH:12][CH:11]=1.C1(N)C(F)=C(F)C(F)=C(N)C=1F.[ClH:31].Cl>[Zn].[Cl-].[NH4+].O.C(O)C>[ClH:31].[ClH:31].[NH2:16][C:13]1[CH:12]=[CH:11][C:10]([NH:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][O:2][CH3:1])=[CH:15][CH:14]=1

Participants

4

Reactant 2

HCID 149026Tetrafluoro-m-phenylenediamine dihydrochlorideHCID 23104369HCID 23104369, compound

Product 1

HCID 23104355HCID 23104355, compound

Reagents, catalysts & solvents 1

HCID 131726756ZINC ammonium chloride water ethanolCatalyst

Procedure

The N-(6-methoxyhexyl)-N-(4-nitrophenyl)amine (16) obtained above was reduced with a boiling zinc/ammonium chloride/water/ethanol mixture. The corresponding amine was isolated in dihydrochloride form.

Sources & evidence

ORD record
ord-a82b84ee4d45487e80c1655ab8050f89
Source dataset
uspto-grants-2008_10
Patent number
US07435267B2

Reaction notes

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