HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl Bromide → 1-Allyl-2-(benzyloxy)-3-tert-butylbenzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl Bromide | HCID 7498 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 2-Allyl-6-t-butylphenol | HCID 520641 | — |
| Catalyst | Tetrabutylammonium Iodide | HCID 67553 | — |
| Solvent | tert-Butanol | HCID 6386 | — |
| Product | 1-Allyl-2-(benzyloxy)-3-tert-butylbenzene | HCID 68964286 | 88% |
Reaction Steps
Treatment of 2-allyl-6-tert-butylphenol (12.5 g, 0.066 mol) with potassium carbonate (27.24 g, 0.197 mol), benzyl bromide (11.80 g, 0.069 mol), and tetrabutylammonium iodide (2.43 g, 6.57 mmol) generally according to the procedure described for Intermediate 1 provided 16.2 g (88%) of 1-allyl-2-(benzyloxy)-3-tert-butylbenzene as a colorless oil. Anal. calcd. for C20H240: C, 85.67; H, 8.63. Found: C, 86.27; H, 8.77.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07435837B2 |
| Source dataset | uspto-grants-2008_10 |
| ORD ID | ord-d316fbcda5f94e3ab44cd3ecbd6b34ca |
| Source note | uspto-grants-2008_10 |