Sodium Perchlorate → HCID 178483693, compound

HRID 2116849Notes

Reaction equation

HRID 2116849 reaction equation
[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[Na+].[CH3:7][N:8]([C:10]([N:13]([CH3:15])[CH3:14])(Cl)[Cl:11])[CH3:9]>O>[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH3:7][N:8]([C+:10]([N:13]([CH3:15])[CH3:14])[Cl:11])[CH3:9]

Participants

4

Reactant 2

HCID 522606Sodium PerchlorateHCID 125447451,1-Dichloro-N,N,N',N'-tetramethylmethanediamine

Product 1

HCID 178483693HCID 178483693, compoundYield 96.7%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

3.60 g of sodium perchlorate in 10 ml of water are added with stirring to a solution of 5.00 g (29.2 mmol) of bis(dimethylamino)dichloromethane in 20 ml of water. The reaction mixture is subsequently stirred for 1 hour with ice-cooling. The residue is filtered off and washed with 10 ml of ice-water and subsequently dried at 50° C. under reduced pressure (7.0 Pa), giving 6.64 g of bis(dimethylamino)chlorocarbenium perchlorate, corresponding to a yield of 94.0%.

Workup

  1. temperaturecooling
  2. filtrationThe residue is filtered off
  3. washwashed with 10 ml of ice-water
  4. customsubsequently dried at 50° C. under reduced pressure (7.0 Pa)

Sources & evidence

ORD record
ord-bfc578e8e6f64046a7b6059121fa75f3
Source dataset
uspto-grants-2008_10
Patent number
US07439395B2

Reaction notes

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