Hydroquinone → HCID 12491640, compound

Participants

Reaction Conditions

Reaction Steps

DCPD (Aldrich, 256.5 mL, 1.9 mol), methyl acrylate (Aldrich, 405 mL, 4.5 mol), and hydroquinone (3.2 g, 0.03 mol) were put in a 2 L autoclave. After heating to 240° C., reaction was carried out for 10 hours while stirring the autoclave at 300 rpm. After the reaction was completed, the reaction mixture was cooled down and transferred to a distillation unit. The reaction mixture was distilled at 1 torr using a vacuum pump at 50° C. to obtain the product (yield: 9.3%). The molar ratio (mol %) of exo/endo isomers of the product was 56.1:33.9.

Provenance & Evidence