HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ammonia → Ammonia
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ammonia | HCID 222 | — |
| Reactant | 1-Methoxyoctane | HCID 70247 | — |
| Product | Ammonia | HCID 222 | — |
| Product | 1-Octene | HCID 8125 | — |
Reaction Steps
Ammonia gas was slowly bubbled through 1-methoxyoctane (50 mL) for 1 hour to form a saturated ammonia solution in 1-methoxyoctane. Analysis of ammonia in methoxyoctane indicated that the solution was saturated after 30 minutes of bubbling (15 min, 2372 mg NH3/L; 30 min, 3016 mg NH3/L; 60 min, 2924 mg NH3/L; 90 min, 3294 mg NH3/L). The NH3 saturated methoxyoctane solution was used as feed to the cracking reactor. The data are presented in Table 3. (NH3 helps to give higher conversion while maintaining high octene-1 selectivity.)
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07442845B2 |
| Source dataset | uspto-grants-2008_10 |
| ORD ID | ord-3779267464b54ace9e7db4494a218cfc |
| Source note | uspto-grants-2008_10 |