HCID 11289583, compound → HCID 11162379, compound

HRID 2118398Notes

Reaction equation

HRID 2118398 reaction equation
COCOC1C=CC2OC(C3C=CC(OCOC)=CC=3)C3CC(O)CC3C=2C=1.[F:29][C@@H:30]1[CH2:50][C@H:33]2[C@@H:34]([C:43]3[CH:48]=[CH:47][C:46]([OH:49])=[CH:45][CH:44]=3)[O:35][C:36]3[CH:37]=[CH:38][C:39]([OH:42])=[CH:40][C:41]=3[C@H:32]2[CH2:31]1>>[F:29][C@H:30]1[CH2:50][C@H:33]2[C@@H:34]([C:43]3[CH:48]=[CH:47][C:46]([OH:49])=[CH:45][CH:44]=3)[O:35][C:36]3[CH:37]=[CH:38][C:39]([OH:42])=[CH:40][C:41]=3[C@H:32]2[CH2:31]1

Participants

3

Reactant 2

HCID 11289583HCID 11289583, compoundHCID 68706007HCID 68706007, compound

Product 1

HCID 11162379HCID 11162379, compound

Procedure

Fluorocyclopentane 47 was prepared from alcohol 27 in a manner substantially similar to fluorocyclopentane 45. HRMS(ES+) calcd for C18H18FO3: 301.1240; found: 301.1241 (M+H).

Sources & evidence

ORD record
ord-a22721a2c2ff46919be77dd1c0652e4c
Source dataset
uspto-grants-2008_10
Patent number
US07442812B2

Reaction notes

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