HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methane → 3-Trisiloxanol, 1,1,1,5,5,5-hexamethyl-3-[(trimethylsilyl)oxy]-, 3-acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methane | HCID 297 | — |
| Reactant | Allyl acetate | HCID 11584 | — |
| Reactant | 1873-89-8 | HCID 2760883 | — |
| Catalyst | Ruthenium | HCID 23950 | — |
| Product | 3-Trisiloxanol, 1,1,1,5,5,5-hexamethyl-3-[(trimethylsilyl)oxy]-, 3-acetate | HCID 5743628 | — |
Reaction Conditions
| Temperature | 105 °C |
|---|
Reaction Steps
A mixture containing 296 g of tris-(trimethylsiloxy)silane, 110 g of allyl acetate and 2.4 g of ruthenium supported on activated charcoal (5 percent by weight of ruthenium and 95 percent by weight of activated charcoal), in which the 2.4 g refers to the total wieght of the charcoal and the ruthenium, are heated to boiling under reflux (approx. 105° C.) for 4 hours. The tris-(trimethylsiloxy)-acetoxysilane yield is quantitative.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04680365 |
| Source dataset | uspto-grants-1987_07 |
| ORD ID | ord-c276a3655369418a9c98b4e16af9681e |
| Source note | uspto-grants-1987_07 |