HCID 69890713, compound → HCID 86586191, compound

HRID 2119710Notes

Reaction equation

HRID 2119710 reaction equation
C([O:5][C:6]1[C:7]([C:21]([CH3:24])([CH3:23])[CH3:22])=[CH:8][C:9]2[O:19][C:12]3([CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13]3)[CH2:11][C:10]=2[CH:20]=1)C=CC>CN(C)C1C=CC=CC=1>[C:21]([C:7]1[C:6]([OH:5])=[C:20]([CH:20]([CH3:10])[CH:6]=[CH2:7])[C:10]2[CH2:11][C:12]3([O:19][C:9]=2[CH:8]=1)[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13]3)([CH3:23])([CH3:24])[CH3:22]

Participants

3

Reactant 1

HCID 69890713HCID 69890713, compound

Product 1

HCID 86586191HCID 86586191, compoundYield 34.1%

Reagents, catalysts & solvents 1

HCID 949N,N-DimethylanilineSolvent

Procedure

0.82 g of 5-(2-butenyloxy)-6-t-butyl-2,3-dihydrobenzofuran-2-spiro-1′-cycloheptane was dissolved in 3 ml of dimethylaniline and the solution was treated in the same manner as in Example 8-2) to give 0.14 g of 6-t-butyl-5-hydroxy-4-(1-methyl-2-propenyl)-2,3-dihydrobenzofuran-2-spiro-1′-cycloheptane as a white solid (yield 17%).

Workup

  1. additionthe solution was treated in the same manner as in Example 8-2)

Sources & evidence

ORD record
ord-9814a46750984bb5a80f4c6adab207cc
Source dataset
uspto-grants-2004_02
Patent number
US06686389B2

Reaction notes

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