HuagongsheHuagongshe Chemistry Print Report · For research reference only
(1H-indol-5-yl)methanol → Indole-5-carboxaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (1H-indol-5-yl)methanol | HCID 2773458 | — |
| Catalyst | Manganese oxide | HCID 160959 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | Indole-5-carboxaldehyde | HCID 589040 | 40.1% |
Reaction Steps
A mixture of (1H-indol-5-yl)-methanol (3.8 g, 25.8 mmol) and manganese oxide (5 g, 57.5 mmol) in dichloromethane (50 mL) was stirred at room temperature for 60 hours. After the usual work-up and chromatography, 1.5 g (40%) of 1H-indole-5-carbaldehyde was obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06689806B1 |
| Source dataset | uspto-grants-2004_02 |
| ORD ID | ord-2db05878f6b749a4a39e3243b99b03a5 |
| Source note | uspto-grants-2004_02 |