HCID 57229336, compound → HCID 9884472, compound

HRID 2120433Notes

Reaction equation

HRID 2120433 reaction equation
[OH:1][C:2]([CH3:25])([CH3:24])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][C:8]1[CH:13]=[CH:12][C:11]([CH:14]=[CH:15][C:16]2[CH:17]=[C:18]([OH:23])[CH:19]=[C:20]([OH:22])[CH:21]=2)=[CH:10][CH:9]=1>[Pd]>[OH:1][C:2]([CH3:25])([CH3:24])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][C:8]1[CH:9]=[CH:10][C:11]([CH2:14][CH2:15][C:16]2[CH:21]=[C:20]([OH:22])[CH:19]=[C:18]([OH:23])[CH:17]=2)=[CH:12][CH:13]=1

Participants

3

Reactant 1

HCID 57229336HCID 57229336, compound

Product 1

HCID 9884472HCID 9884472, compound

Reagents, catalysts & solvents 1

HCID 23938PalladiumCatalyst

Procedure

In a manner similar to Example 9(a), by reacting 1 g (2.9 mmol) of 5-{2-[4-(6-hydroxy-6-methylheptyl)phenyl]vinyl}benzene-1,3-diol with 100 mg of 10% palladium/carbon, whitish crystals (m=728 mg; Y=91%) are obtained. m.p.=128-30° C.

Workup

  1. customare obtained

Sources & evidence

ORD record
ord-87970537a5e047af9335be142cbdd5dd
Source dataset
uspto-grants-2004_02
Patent number
US06689922B1

Reaction notes

Loading…