HCID 57074631, compound → HCID 9906718, compound

HRID 2120436Notes

Reaction equation

HRID 2120436 reaction equation
[OH:1][CH2:2][C:3]1[CH:8]=[C:7]([CH:9]=[CH:10][C:11]2[CH:16]=[CH:15][CH:14]=[C:13]([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][C:22]([OH:25])([CH3:24])[CH3:23])[CH:12]=2)[CH:6]=[CH:5][C:4]=1[OH:26]>[Pd]>[OH:1][CH2:2][C:3]1[CH:8]=[C:7]([CH2:9][CH2:10][C:11]2[CH:16]=[CH:15][CH:14]=[C:13]([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][C:22]([OH:25])([CH3:23])[CH3:24])[CH:12]=2)[CH:6]=[CH:5][C:4]=1[OH:26]

Participants

3

Reactant 1

HCID 57074631HCID 57074631, compound

Product 1

HCID 9906718HCID 9906718, compound

Reagents, catalysts & solvents 1

HCID 23938PalladiumCatalyst

Procedure

In a manner similar to Example 9(a), by reacting 97 mg (0.27 mmol) of 2-hydroxymethyl-4-{2-[3-(6-hydroxy-6-methylheptyl)phenyl]vinyl}phenol with 27 mg of 10% palladium/carbon, yellowish crystals (m=70 mg; Y=73%) are obtained. m.p.=73-5° C.

Workup

  1. customare obtained

Sources & evidence

ORD record
ord-a7d992d6a9c84057ba366a7505c3bc35
Source dataset
uspto-grants-2004_02
Patent number
US06689922B1

Reaction notes

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