HCID 57117816, compound → HCID 9863533, compound

HRID 2120437Notes

Reaction equation

HRID 2120437 reaction equation
[OH:1][CH2:2][C:3]1[CH:8]=[C:7]([CH:9]=[CH:10][C:11]2[CH:16]=[CH:15][C:14]([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][C:22]([OH:25])([CH3:24])[CH3:23])=[CH:13][CH:12]=2)[CH:6]=[CH:5][C:4]=1[OH:26]>[Pd]>[OH:1][CH2:2][C:3]1[CH:8]=[C:7]([CH2:9][CH2:10][C:11]2[CH:12]=[CH:13][C:14]([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][C:22]([OH:25])([CH3:23])[CH3:24])=[CH:15][CH:16]=2)[CH:6]=[CH:5][C:4]=1[OH:26]

Participants

3

Reactant 1

HCID 57117816HCID 57117816, compound

Product 1

HCID 9863533HCID 9863533, compound

Reagents, catalysts & solvents 1

HCID 23938PalladiumCatalyst

Procedure

In a manner similar to Example 9(a), by reacting 150 mg (0.42 mmol) of 2-hydroxymethyl-4-{2-[4-(6-hydroxy-6-methylheptyl)phenyl]vinyl}phenol with 42 mg of 10% palladium/carbon, crystals (m=65 mg; Y=43%) are obtained. m.p.=110-1° C.

Workup

  1. customare obtained

Sources & evidence

ORD record
ord-377fa8066c8c40f68084776875bdf4a4
Source dataset
uspto-grants-2004_02
Patent number
US06689922B1

Reaction notes

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