HuagongsheHuagongshe Chemistry Print Report · For research reference only
Lithium borohydride → (E)-7-[3-(3,4-bis-Hydroxymethylbenzyloxy)phenyl]-3-ethyloct-6-en-3-ol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Lithium borohydride | HCID 4148881 | — |
| Reactant | dimethyl 4-[3-((E)-5-ethyl-5-hydroxy-1-methylhept-1-enyl)phenoxymethyl]phthalate | HCID 23439764 | — |
| Product | (E)-7-[3-(3,4-bis-Hydroxymethylbenzyloxy)phenyl]-3-ethyloct-6-en-3-ol | HCID 67533486 | — |
Reaction Steps
In a manner similar to Example 53(e), by reacting 131 mg (0.29 mmol) of dimethyl 4-[3-((E)-5-ethyl-5-hydroxy-1-methylhept-1-enyl)phenoxymethyl]phthalate with 25 mg (1.15 mmol) of lithium borohydride, a colourless oil is obtained (m=89 mg; Y=78%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06689922B1 |
| Source dataset | uspto-grants-2004_02 |
| ORD ID | ord-215de56286014425a6b4ad59faa62455 |
| Source note | uspto-grants-2004_02 |