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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2120520Generated: November 2, 2026

Tert-dodecanethiol → Methacrylic Acid

https://huagongshe.com/reaction/2120520

Reaction equation

Participants

RoleNameHCIDCharge
ReactantTert-dodecanethiolHCID 32793—
ReactantHCID 18364573HCID 18364573—
ProductMethacrylic AcidHCID 4093—
ProductMethyl MethacrylateHCID 6658—
Producttert-Butyl methacrylateHCID 11448—

Reaction Steps

Using azoisobutyronitrile as a polymerization initiator and t-dodecylmercaptan as a chain transfer agent, a t-butyl methacrylate, methyl methacrylate and methacrylic acid were polymerized to obtain a copolymer having a t-butyl methacrylate/methyl methacrylate/methacrylic acid compositional ratio of 40/50/10 and an Mw of 25,000. This copolymer is designated as acid-cleavable additive C1.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS06692887B1
Source datasetuspto-grants-2004_02
ORD IDord-4f30d8aefafb4db1bdccf6c67f2cf8e6
Source noteuspto-grants-2004_02