4-Vinylpyridine → HCID 22975755, compound

HRID 2120965Notes

Reaction equation

HRID 2120965 reaction equation
Cl.NN=CC1C=CC([C:9]([N:11]2[CH2:16][CH2:15][C:14]3([CH2:21][CH2:20][CH:19]([CH2:22][C:23]([O:25][CH2:26][CH3:27])=[O:24])[CH2:18][CH2:17]3)[CH2:13][CH2:12]2)=O)=CC=1.[CH:30]([C:32]1[CH:37]=[CH:36][N:35]=[CH:34][CH:33]=1)=C>C(#N)C>[N:35]1[CH:36]=[CH:37][C:32]([CH2:30][CH2:9][N:11]2[CH2:16][CH2:15][C:14]3([CH2:21][CH2:20][CH:19]([CH2:22][C:23]([O:25][CH2:26][CH3:27])=[O:24])[CH2:18][CH2:17]3)[CH2:13][CH2:12]2)=[CH:33][CH:34]=1

Participants

4

Reactant 2

HCID 75024-VinylpyridineHCID 86584289HCID 86584289, compound

Product 1

HCID 22975755HCID 22975755, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

A solution of 0.48 g (2.0 mmol) of the intermediate from Example 1. Step C and 0.21 g (2.0 mmol) 4-vinylpyridine in 6 ml acetonitrile were heated at 80° C. over night. The solvent was removed under reduced pressure, and the remaining solid title compound was purified by stirring several times with tert.-butylmethylether, filtered with suction, and dried in vacuo.

Workup

  1. customThe solvent was removed under reduced pressure
  2. customthe remaining solid title compound was purified
  3. filtrationfiltered with suction
  4. customdried in vacuo

Sources & evidence

ORD record
ord-642ff825522b4cadae241c29b974ee00
Source dataset
uspto-grants-2004_02
Patent number
US06693109B2

Reaction notes

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