HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Methyl-2-methylthioquinolinium p-toluenesulfonate → 3-[3-Benzyl-5-(1-methyl-1H-quinolin-2-ylidene)-4-oxothiazolidin-2-ylideneamino]-4-ethylaminobenzonitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Methyl-2-methylthioquinolinium p-toluenesulfonate | HCID 15597093 | — |
| Reactant | 3-(3-Benzyl-4-oxothiazolidin-2-ylideneamino)-4-ethylaminobenzonitrile | HCID 21937376 | — |
| Product | 3-[3-Benzyl-5-(1-methyl-1H-quinolin-2-ylidene)-4-oxothiazolidin-2-ylideneamino]-4-ethylaminobenzonitrile | HCID 73855019 | — |
Reaction Steps
In a manner similar to Example 45, intermediate 1-methyl-2-methylthioquinolinium p-toluenesulfonate was condensed with 3-(3-benzyl-4-oxothiazolidin-2-ylideneamino)-4-ethylaminobenzonitrile to afford the title compound. 1H-NMR (CDCl3): δ 7.41-7.58 (4H, m), 7.20-7.38 (9H, m), 6.49 (1H, d), 5.16 (2H, s), 3.79 (3, br s), 3.01 (2H, q), 1.02 (3H, t); MS(ESI): 492 (MH+).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06696473B2 |
| Source dataset | uspto-grants-2004_02 |
| ORD ID | ord-c987cf9ec487437986793bc365079218 |
| Source note | uspto-grants-2004_02 |