HCID 527879, compound → HCID 74052928, compound

HRID 2122092Notes

Reaction equation

HRID 2122092 reaction equation
[C:1]([O:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][Cl:13])(=[O:3])[CH3:2].C(OCCCCC=CCCCCOC(=O)C)(=O)C.ClCCC=CCCCl>>[C:1]([O:4][CH2:5][CH2:6][CH2:7][CH2:8][CH:9]=[CH:10][CH2:11][CH2:12][Cl:13])(=[O:3])[CH3:2]

Participants

4

Reactant 3

HCID 527879HCID 527879, compoundHCID 53981582HCID 53981582, compoundHCID 72775720HCID 72775720, compound

Product 1

HCID 74052928HCID 74052928, compound

Procedure

FIG. 24A shows a synthesis of 8-chlorooctan-1-yl acetate, in which 1,10-diacetoxy-5-decene is cross-metathesized with 1,6-dichloro-3-hexene to yield 8-chloro-5-octen-1-yl acetate, which is reduced to yield 8-chlorooctanyl acetate.

Sources & evidence

ORD record
ord-1c7b96f29bf747b9a16a20c7f63a2d29
Source dataset
uspto-grants-2004_02
Patent number
US06696597B2

Reaction notes

Loading…