Potassium Cation → 1-Benzyloxycarbonyl-5-chloro-3-hydroxymethylindole

HRID 2125779Notes

Reaction equation

HRID 2125779 reaction equation
[BH4-:23].[C:26](=[O:27])([O-:28])[O-:29].[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][C:9](=[O:10])[n:11]1[cH:12][c:13]([CH:21]=[O:22])[c:14]2[cH:15][c:16]([Cl:20])[cH:17][cH:18][c:19]12.[CH3:32][OH:33].[CH3:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39].[K+:30].[K+:31].[Na+:24].[OH2:25]>>[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][C:9](=[O:10])[n:11]1[cH:12][c:13]([CH2:21][OH:22])[c:14]2[cH:15][c:16]([Cl:20])[cH:17][cH:18][c:19]12

Participants

9

Reactant 8

HCID 813Potassium Cation2×HCID 887MethanolHCID 923Sodium ionHCID 962WaterHCID 8058HexaneHCID 19660Carbonate IonHCID 28123BorohydrideHCID 184739871-Benzyloxycarbonyl-5-chloro-3-formylindol

Product 1

HCID 184739211-Benzyloxycarbonyl-5-chloro-3-hydroxymethylindole

Sources & evidence

ORD record
ord-c92035f3ab0d43a1985bdc1cc38cb977
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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