Acetone → Ethyl(2'-oxo-5,6-dihydrospiro[benzo[1,2-b:5,4-b']difuran-3,3'-indol]-1'(2'h)-yl)acetate

HRID 2126482Notes

Reaction equation

HRID 2126482 reaction equation
[Br:22][CH2:23][C:24](=[O:25])[O:26][CH2:27][CH3:28].[C:29](=[O:30])([O-:31])[O-:32].[CH3:35][C:36](=[O:37])[CH3:38].[Cs+:33].[Cs+:34].[NH:1]1[C:2](=[O:21])[C:3]2([c:4]3[c:5]([cH:8][c:9]4[c:13]([cH:14]3)[CH2:12][CH2:11][O:10]4)[O:6][CH2:7]2)[c:15]2[cH:16][cH:17][cH:18][cH:19][c:20]21>>[N:1]1([CH2:23][C:24](=[O:25])[O:26][CH2:27][CH3:28])[C:2](=[O:21])[C:3]2([c:4]3[c:5]([cH:8][c:9]4[c:13]([cH:14]3)[CH2:12][CH2:11][O:10]4)[O:6][CH2:7]2)[c:15]2[cH:16][cH:17][cH:18][cH:19][c:20]21

Participants

6

Reactant 5

HCID 180AcetoneHCID 7748Ethyl bromoacetateHCID 19660Carbonate IonHCID 104967Cesium cation2×HCID 592633545,6-dihydro-2H-spiro[benzofuro[6,5-b]furan-3,3'-indolin]-2'-one

Product 1

HCID 59263427Ethyl(2'-oxo-5,6-dihydrospiro[benzo[1,2-b:5,4-b']difuran-3,3'-indol]-1'(2'h)-yl)acetate

Sources & evidence

ORD record
ord-ed0f507803d9404bacce5477adfdd788
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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