Potassium Cation → [S-(R,S)]-Phenylmethyl [1-oxiranyl-2-(phenylthio)ethyl]carbamate

HRID 2130113Notes

Reaction equation

HRID 2130113 reaction equation
[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][C:9](=[O:10])[NH:11][CH:12]([CH:13]([CH2:14][O:15][C:21](=[O:22])[c:23]1[cH:24][cH:25][c:26]([N+:27]([O-:28])=[O:29])[cH:30][cH:31]1)[O:16][S:17]([CH3:18])(=[O:19])=[O:20])[CH2:32][S:33][c:34]1[cH:35][cH:36][cH:37][cH:38][cH:39]1.[CH2:49]1[O:50][CH2:51][CH2:52][O:53][CH2:54]1.[CH3:42][c:43]1[cH:44][cH:45][cH:46][cH:47][cH:48]1.[K+:41].[OH-:40]>>[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][C:9](=[O:10])[NH:11][CH:12]([CH:13]1[CH2:14][O:15]1)[CH2:32][S:33][c:34]1[cH:35][cH:36][cH:37][cH:38][cH:39]1

Participants

6

Reactant 5

HCID 813Potassium CationHCID 961HydroxideHCID 1140TolueneHCID 312751,4-DioxaneHCID 21255967[2-Methylsulfonyloxy-3-(phenylmethoxycarbonylamino)-4-phenylsulfanylbutyl] 4-nitrobenzoate

Product 1

HCID 22141446[S-(R,S)]-Phenylmethyl [1-oxiranyl-2-(phenylthio)ethyl]carbamate

Sources & evidence

ORD record
ord-f5220e923f994052a54748f461c4e340
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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