Acetone → 11-Acetyl-4-formyl-9-hydroxy-6-methoxy-14-oxa-1,11-diazatetracyclo[7.4.1.02,7.010,12]tetradeca-2,4,6-trien-8-ylmethyl carbamate

HRID 2132030Notes

Reaction equation

HRID 2132030 reaction equation
[C:1]([NH2:2])([O:3][CH2:4][CH:5]1[c:6]2[c:7]([OH:25])[cH:8][c:9]([CH:23]=[O:24])[cH:10][c:11]2[N:12]2[CH2:13][CH:14]3[N:15]([C:20]([CH3:21])=[O:22])[CH:16]3[C:17]1([OH:19])[O:18]2)=[O:26].[C:27](=[O:28])([O-:29])[O-:30].[CH3:33][C:34](=[O:35])[CH3:36].[CH3:37][I:38].[K+:31].[K+:32]>>[C:1]([NH2:2])([O:3][CH2:4][CH:5]1[c:6]2[c:7]([O:25][CH3:27])[cH:8][c:9]([CH:23]=[O:24])[cH:10][c:11]2[N:12]2[CH2:13][CH:14]3[N:15]([C:20]([CH3:21])=[O:22])[CH:16]3[C:17]1([OH:19])[O:18]2)=[O:26]

Participants

6

Reactant 5

HCID 180AcetoneHCID 813Potassium Cation2×HCID 6328Methyl iodideHCID 19660Carbonate IonHCID 3035469FR 66980

Product 1

HCID 990772711-Acetyl-4-formyl-9-hydroxy-6-methoxy-14-oxa-1,11-diazatetracyclo[7.4.1.02,7.010,12]tetradeca-2,4,6-trien-8-ylmethyl carbamate

Sources & evidence

ORD record
ord-b2dfcee59402480e95f3ae41d9004266
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

Loading…