Acetate → 4-Carbomethoxy-3'-Acetylbiphenyl

HRID 2136434Notes

Reaction equation

HRID 2136434 reaction equation
[C:1]([CH3:2])(=[O:3])[c:4]1[cH:5][c:6]([B:10]([OH:11])[OH:12])[cH:7][cH:8][cH:9]1.[C:26]([O-:27])(=[O:28])[CH3:29].[C:31]([O-:32])(=[O:33])[CH3:34].[CH3:15][O:16][C:17]([c:18]1[cH:19][cH:20][c:21]([Cl:24])[cH:22][cH:23]1)=[O:25].[F-:13].[K+:14].[Pd+2:30]>>[C:1]([CH3:2])(=[O:3])[c:4]1[cH:5][c:6](-[c:21]2[cH:20][cH:19][c:18]([C:17]([O:16][CH3:15])=[O:25])[cH:23][cH:22]2)[cH:7][cH:8][cH:9]1

Participants

7

Reactant 6

HCID 175Acetate2×HCID 813Potassium CationHCID 14307Methyl 4-chlorobenzoateHCID 28179Fluoride IonHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 27343103-Acetylphenylboronic acid

Product 1

HCID 43288044-Carbomethoxy-3'-Acetylbiphenyl

Sources & evidence

ORD record
ord-5295e360de1d4f0bacbf5f3190e59012
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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