HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl iodide → 4-Methoxymethyl-1-methyl-pyridinium iodide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl iodide | HCID 6328 | — |
| Reactant | 4-(Methoxymethyl)pyridine | HCID 642837 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | 4-Methoxymethyl-1-methyl-pyridinium iodide | HCID 14442208 | 88% |
Reaction Steps
A solution of 4.8 g (0.039 mol) of 4-methoxymethyl-pyridine in 25 ml of acetonitrile is mixed with 6.6 g (0.047 mol) of methyl iodide and stirred for 5 hours at ambient temperature. Then the partially precipitated quaternary salt is precipitated by the addition of ethyl acetate. 9.1 g (88% of theory) of 4-methoxymethyl-1-methyl-pyridinium iodide are obtained, m.p. 105°-108° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05422353 |
| Source dataset | uspto-grants-1995_06 |
| ORD ID | ord-5b2866a54c594fe0988446603115cc4e |
| Source note | uspto-grants-1995_06 |