Sodium ion → 9-bromo-2-hydroxy-5-(3-pyridylmethyl)-4H-pyrido [3,2,1-jk]carbazole-4-one

HRID 2139800Notes

Reaction equation

HRID 2139800 reaction equation
[B:28]([Br:29])([Br:30])[Br:31].[Br:1][c:2]1[cH:3][c:4]2[n:5]3[c:6]4[c:7]([cH:8][c:9]([O:15][CH3:16])[cH:10][c:11]4[c:12]2[cH:13][cH:14]1)[c:17](=[O:27])[c:18]([CH2:20][c:21]1[cH:22][n:23][cH:24][cH:25][cH:26]1)[cH:19]3.[CH2:39]([Cl:40])[Cl:41].[Na+:33].[Na+:34].[O-:35][C:36](=[O:37])[O-:38].[OH2:32]>>[Br:1][c:2]1[cH:3][c:4]2[n:5]3[c:6]4[c:7]([cH:8][c:9]([OH:15])[cH:10][c:11]4[c:12]2[cH:13][cH:14]1)[c:17](=[O:27])[c:18]([CH2:20][c:21]1[cH:22][n:23][cH:24][cH:25][cH:26]1)[cH:19]3

Participants

7

Reactant 6

HCID 923Sodium ion2×HCID 962WaterHCID 6344DichloromethaneHCID 19660Carbonate IonHCID 25134Boron tribromideHCID 193648679-bromo-2-methoxy-5-(3-pyridylmethyl)-4H-pyrido [3,2,1-jk]carbazole-4-one

Product 1

HCID 212528709-bromo-2-hydroxy-5-(3-pyridylmethyl)-4H-pyrido [3,2,1-jk]carbazole-4-one

Sources & evidence

ORD record
ord-ff383d519a5d4cfe99c427fcf14178ea
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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