Dichloromethane → tert-butyl 2-formyl-4H,5H,6H,7H-thieno[3,2-c]pyridine-5-carboxylate

HRID 2141010Notes

Reaction equation

HRID 2141010 reaction equation
[CH2:19]([Cl:20])[Cl:21].[O:22]=[Mn:23]=[O:24].[OH:1][CH2:2][c:3]1[cH:4][c:5]2[c:10]([s:11]1)[CH2:9][CH2:8][N:7]([C:12](=[O:13])[O:14][C:15]([CH3:16])([CH3:17])[CH3:18])[CH2:6]2>>[O:1]=[CH:2][c:3]1[cH:4][c:5]2[c:10]([s:11]1)[CH2:9][CH2:8][N:7]([C:12](=[O:13])[O:14][C:15]([CH3:16])([CH3:17])[CH3:18])[CH2:6]2

Participants

4

Reactant 3

HCID 6344DichloromethaneHCID 14801Manganese dioxideHCID 118456061,1-Dimethylethyl 6,7-dihydro-2-(hydroxymethyl)thieno[3,2-c]pyridine-5(4H)-carboxylate

Product 1

HCID 11845085tert-butyl 2-formyl-4H,5H,6H,7H-thieno[3,2-c]pyridine-5-carboxylate

Sources & evidence

ORD record
ord-4323db8cc8e64f1fb7b4465058cf7f47
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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