Methyl {o-[5-(methoxymethoxy)-2-nitrophenoxy]phenoxy}acetate → Methyl [p-(5-hydroxy-2-nitrophenoxy)phenoxy]acetate

HRID 21515Notes

Reaction equation

HRID 21515 reaction equation
COC[O:4][C:5]1[CH:6]=[CH:7][C:8]([N+:24]([O-:26])=[O:25])=[C:9]([CH:23]=1)[O:10][C:11]1[CH:22]=[CH:21][C:14]([O:15][CH2:16][C:17]([O:19][CH3:20])=[O:18])=[CH:13][CH:12]=1.COCOC1C=CC([N+]([O-])=O)=C(C=1)OC1C=CC=CC=1OCC(OC)=O>>[OH:4][C:5]1[CH:6]=[CH:7][C:8]([N+:24]([O-:26])=[O:25])=[C:9]([CH:23]=1)[O:10][C:11]1[CH:22]=[CH:21][C:14]([O:15][CH2:16][C:17]([O:19][CH3:20])=[O:18])=[CH:13][CH:12]=1

Participants

3

Reactant 2

HCID 54326397Methyl {o-[5-(methoxymethoxy)-2-nitrophenoxy]phenoxy}acetateHCID 54353747Methyl {p-[5-(methoxymethoxy)-2-nitrophenoxy]phenoxy}acetate

Product 1

HCID 53848901Methyl [p-(5-hydroxy-2-nitrophenoxy)phenoxy]acetate

Procedure

Using essentially the same procedure, but subtituting methyl {p-[5-(methoxymethoxy)-2-nitrophenoxy]phenoxy}acetate for methyl {o-[5-(methoxymethoxy)-2-nitrophenoxy]phenoxy}acetate, methyl [p-(5-hydroxy-2-nitrophenoxy)phenoxy]acetate is obtained.

Sources & evidence

ORD record
ord-ad5efb7e19be4f6083551db151bec1bd
Source dataset
uspto-grants-1995_06
Patent number
US05424280

Reaction notes

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