Methanol → methyl 3,11-dihydroxy-10,13-dimethyl-2,3,4,5,6,7,8,9,11,12,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthrene-17-carboxylate

HRID 2155966Notes

Reaction equation

HRID 2155966 reaction equation
[BH4-:1].[CH3:29][OH:30].[Na+:2].[OH2:28].[OH:3][CH:4]1[CH2:5][CH:6]2[CH2:7][CH2:8][CH:9]3[CH:10]4[CH2:11][CH2:12][CH:13]([C:24](=[O:25])[O:26][CH3:27])[C:14]4([CH3:15])[CH2:16][C:17](=[O:23])[CH:18]3[C:19]2([CH3:22])[CH2:20][CH2:21]1>>[OH:3][CH:4]1[CH2:5][CH:6]2[CH2:7][CH2:8][CH:9]3[CH:10]4[CH2:11][CH2:12][CH:13]([C:24](=[O:25])[O:26][CH3:27])[C:14]4([CH3:15])[CH2:16][CH:17]([OH:23])[CH:18]3[C:19]2([CH3:22])[CH2:20][CH2:21]1

Participants

6

Reactant 5

HCID 887MethanolHCID 923Sodium ionHCID 962WaterHCID 28123BorohydrideHCID 178497071HCID 178497071, compound

Product 1

HCID 20347616methyl 3,11-dihydroxy-10,13-dimethyl-2,3,4,5,6,7,8,9,11,12,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthrene-17-carboxylate

Sources & evidence

ORD record
ord-e2ec72a6ab774532807c4b0c01b2d338
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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