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HRID2163364

反应详情

EQUATION

反应方程式

HRID 2163364 的结构方程式

REACTANTS

反应物

2
结构：CNC
HCID674

Dimethylamine

C2H7N

结构：CC1(C)C=C(c2cccc3ccccc23)c2ccc(OCC3CO3)cc2O1
HCID23330742

2,2-Dimethyl-4-(naphthalen-1-yl)-7-[(oxiran-2-yl)methoxy]-2H-1-benzopyran

C24H22O3

PRODUCTS

生成物

1
结构：CN(C)CC(O)COc1ccc2c(c1)OC(C)(C)C=C2c1cccc2ccccc12
HCID54179358

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCO
溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

7-(2,3-Epoxypropoxy)-2,2-dimethyl-4-(1-naphthyl)-2H-chromene (4.4g., 0.012 moles) was dissolved in a solution of dimethylamine in ethanol (28ml., ~40% solution) and left to stand at room temperature for 48 hours. Removal of solvent gave the title product as an orange oil which was converted to the hydrochloride salt. Recrystallization from acetone gave a white solid (3.13g., 64%) m.p. 185-187° C.

WORKUP

后处理

  1. waitleft
  2. customRemoval of solvent