4-Ethylphenol → HCID 22749891, compound

HRID 2164191Notes

Reaction equation

HRID 2164191 reaction equation
S([O-])(=O)(=O)C.[CH3:6][O:7][C:8]([CH3:18])([CH3:17])[CH2:9][CH2:10][CH2:11][CH:12]([CH3:16])[CH2:13][CH2:14][OH:15].[CH3:19][O:20][C:21]([CH3:31])([CH3:30])[CH2:22][CH2:23][CH2:24][C:25]([CH3:29])=[CH:26][CH2:27][OH:28].COC(C)(C)CCCC(O)C.[CH2:43]([C:45]1[CH:50]=[CH:49][C:48](O)=[CH:47][CH:46]=1)[CH3:44]>>[CH2:26]([C:25]1[CH:31]=[CH:21][C:22]([O:15][CH2:14][CH2:13][CH:12]([CH3:16])[CH2:11][CH2:10][CH2:9][C:8]([O:7][CH3:6])([CH3:17])[CH3:18])=[CH:23][CH:24]=1)[CH3:27].[CH2:43]([C:45]1[CH:50]=[CH:49][C:48]([O:28][CH2:27][CH:26]=[C:25]([CH3:29])[CH2:24][CH2:23][CH2:22][C:21]([O:20][CH3:19])([CH3:31])[CH3:30])=[CH:47][CH:46]=1)[CH3:44]

Participants

7

Reactant 5

HCID 312424-EthylphenolHCID 85257MethanesulfonateHCID 1700411-Octanol, 7-methoxy-3,7-dimethyl-HCID 13676286HCID 13676286, compoundHCID 53709797HCID 53709797, compound

Product 2

HCID 22749891HCID 22749891, compoundHCID 538206451-Ethyl-4-[(7-methoxy-3,7-dimethyloct-2-en-1-yl)oxy]benzene

Procedure

The mesylate of each of 7-methoxy-3,7-dimethyloctan-1-ol, 7-methoxy-3,7-dimethyloct-2-en-1-ol and 6-methoxy-6-methylheptan-2-ol is reacted with p-ethylphenol using the process of Example 10(D) to yield 7-methoxy-3,7-dimethyloctyl p-ethylphenyl ether, 7-methoxy-3,7-dimethyloct-2-enyl p-ethylphenyl ether and 6-methoxy-6-methylhept-2-yl p-phenyl ether (5-methoxy-1,5-dimethylhexyl p-ethylphenyl ether).

Sources & evidence

ORD record
ord-3754a3bcd13045599742ed8aef602bcf
Source dataset
uspto-grants-1979_01
Patent number
US04137273

Reaction notes

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