Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 4-Ethylthiophenol | HCID 2758914 | — |
| Reactant | HCID 13788887 | HCID 13788887 | — |
| Reactant | 1-Bromo-7-ethoxy-3,7-dimethyloctane | HCID 22749742 | — |
| Reactant | 1-Bromo-7-ethoxy-3,7-dimethyloct-2-ene | HCID 54263253 | — |
| Reactant | HCID 54489253 | HCID 54489253 | — |
| Product | HCID 22749734 | HCID 22749734 | — |
| Product | HCID 22749863 | HCID 22749863 | — |
| Product | HCID 53908595 | HCID 53908595 | — |
| Product | HCID 54087525 | HCID 54087525 | — |
Reaction Steps
By using the process of either Example 4 or 13, each of 1-bromo-7-methoxy-3,7-dimethyloctane, 1-bromo-7-ethoxy-3,7-dimethyloctane, 1-bromo-7-methoxy-3,7-dimethyloct-2-ene and 1-bromo-7-ethoxy-3,7-dimethyloct-2-ene is reacted with p-ethylphenyl mercaptan to yield 7-methoxy-3,7-dimethyloctyl p-ethylphenyl sulfide, 7-ethoxy-3,7-dimethyloctyl p-ethylphenyl sulfide, 7-methoxy-3,7-dimethyloct-2-enyl p-ethylphenyl sulfide and 7-ethoxy-3,7-dimethyloct-2-enyl p-ethylphenyl sulfide, respectively. By use of the processes of Examples 6 and 7, the corresponding sulfoxides and sulfones, respectively, are prepared, e.g. 7-methoxy-3,7-dimethyloctyl p-ethylphenyl sulfoxide, 7-ethoxy-3,7-dimethyloctyl p-ethylphenyl sulfoxide, 7-methoxy-3,7-dimethyloctyl p-ethylphenyl sulfone and 7-ethoxy-3,7-dimethyloctyl p-ethylphenyl sulfone and the corresponding 2,3-dehydro compounds.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04137273 |
|---|
| Source dataset | uspto-grants-1979_01 |
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| ORD ID | ord-784ab8b38a0346be8a3e06410d488091 |
|---|
| Source note | uspto-grants-1979_01 |
|---|
