HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → 2,4,8,10-Tetra-t-butyl-12H-dibenzo[d,g][1,3,2]dioxasilocin
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Dichlorosilane | HCID 61330 | — |
| Reactant | 2,2'-Methylenebis(4,6-di-tert-butylphenol) | HCID 84391 | — |
| Reactant | Acetone cardice | HCID 18522661 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 2,4,8,10-Tetra-t-butyl-12H-dibenzo[d,g][1,3,2]dioxasilocin | HCID 102330274 | 57.2% |
Reaction Steps
In a flame-dried flask equiped with a dry ice-acetone filled Dewar condenser and a sintered glass inlet, 42.5 grams (0.1 mole) 2,2'-methylene-bis(4,6-di-t-butylphenol) and 20.2 grams (0.2 mole) triethylamine dissolved in 100 ml tetrahydrofuran are treated slowly with 11.1 grams (0.11 mole) dichlorosilane. Filtration and recrystallization from acetonitrile-toluene gave 25.9 grams (57% yield) of a white solid mp 189°-192° C. The 1H NMR spectrum is consistent with the product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04503243 |
| Source dataset | uspto-grants-1985_03 |
| ORD ID | ord-621f060752254482a57b0d4d085faa35 |
| Source note | uspto-grants-1985_03 |