Sodium Methoxide → HCID 74089434, compound

HRID 2164372Notes

Reaction equation

HRID 2164372 reaction equation
C[O-].[Na+:3].[CH2:4]([O:6][N:7]=[C:8]([C:11]1[C:12](=[O:28])[CH2:13][CH:14]([C:18]2[CH:23]=[CH:22][C:21]([C:24]([O:26][CH3:27])=[O:25])=[CH:20][CH:19]=2)[CH2:15][C:16]=1[OH:17])[CH2:9][CH3:10])[CH3:5]>CO>[CH2:4]([O:6][N:7]=[C:8]([C:11]1[C:16](=[O:17])[CH2:15][CH:14]([C:18]2[CH:19]=[CH:20][C:21]([C:24]([O:26][CH3:27])=[O:25])=[CH:22][CH:23]=2)[CH2:13][C:12]=1[O-:28])[CH2:9][CH3:10])[CH3:5].[Na+:3]

Participants

4

Reactant 2

HCID 10942334Sodium MethoxideHCID 136196406HCID 136196406, compound

Product 1

HCID 74089434HCID 74089434, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Into 10.8 g of methanol containing 2.5% of sodium methoxide was dissolved 1.7 g of 2-[1-(ethoxyimino)propyl]-3-hydroxy-5-(4-methoxycarbonylphenyl)-2-cyclohexen-1-one and the solvent was removed from it under reduced pressure. Thus, 1.8 g of colorless desired crystals were obtained.

Workup

  1. customthe solvent was removed from it under reduced pressure

Sources & evidence

ORD record
ord-c5214ee951a04e12b0e7b75b1fe91984
Source dataset
uspto-grants-1985_03
Patent number
US04504305

Reaction notes

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