3-(3-Pyridyl)-D-alanine → D-Tryptophan

HRID 2164379Notes

Reaction equation

HRID 2164379 reaction equation
N[C@@H:2]([C:10](O)=O)[CH2:3]C1N=CC=CC=1.[NH2:13][C@@H:14]([C:22]([OH:24])=[O:23])[CH2:15][C:16]1[CH:21]=[N:20][CH:19]=[CH:18][CH:17]=1.N[C@@H](C(O)=O)CC1C=CN=CC=1>>[CH:3]1[CH:2]=[CH:10][C:19]2[NH:20][CH:21]=[C:16]([CH2:15][C@@H:14]([NH2:13])[C:22]([OH:24])=[O:23])[C:18]=2[CH:17]=1

Participants

4

Reactant 3

HCID 12681443-(3-Pyridyl)-D-alanineHCID 7009693(alphaR)-alpha-Amino-4-pyridinepropanoic acidHCID 70197683-(2-Pyridyl)-D-alanine

Product 1

HCID 9060D-Tryptophan

Procedure

with at least one of position 3 or 6 being D-2-Pal, D-3-Pal, or D-4-Pal; and

Sources & evidence

ORD record
ord-40b943111ad54326b3dc60e14e9e1931
Source dataset
uspto-grants-1985_03
Patent number
US04504414

Reaction notes

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