Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Glyoxal | HCID 7860 | — |
| Reactant | 3,6-Dimethoxybenzene-1,2-diamine | HCID 11629660 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 600389 | HCID 600389 | 75.4% |
Reaction Steps
A mixture of 10 g (0.17 mol) of glyoxal in 50 ml of water was added to 5 g (0.03 mol) of 2,3-diaminohydroquinone dimethyl ether, and stirred at 50° C. for 1 hour. After allowing to cool to room temperature, the reaction solution was extracted with chloroform, and the extract was dried and concentrated. Recrystallization of the residue from benzene gave 4.3 g (75%) of the title compound. m.p. 145°-150° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04506001 |
|---|
| Source dataset | uspto-grants-1985_03 |
|---|
| ORD ID | ord-2dde7af0170044a18234374c1b9dd81f |
|---|
| Source note | uspto-grants-1985_03 |
|---|
