Benzene → HCID 14550424, compound

HRID 2164711Notes

Reaction equation

HRID 2164711 reaction equation
[C:1]([O-])(=[O:4])[CH2:2]C.[Sc+3:6].[C:7]([O-])(=[O:10])[CH2:8]C.[C:12]([O-])(=[O:15])[CH2:13]C.C1C=CC=CC=1.[Li]>C(O)C>[O-:4][CH2:1][CH3:2].[Sc+3:6].[O-:10][CH2:7][CH3:8].[O-:15][CH2:12][CH3:13]

Participants

5

Reactant 3

HCID 241BenzeneHCID 3028194Lithium2×HCID 86739995HCID 86739995, compound

Product 1

HCID 14550424HCID 14550424, compoundYield 118.4%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

Scandium propionate (0.03 mol.), benzene (50 ml) and ethanol (10 ml) were placed in a round-bottomed flask of 100 ml-capacity, to which was then added slowly 0.6 g (0.09 mol.) of metallic lithium under stirring. After the addition of the metallic lithium, the admixture in the flask was refluxed for 1 hour by heating with aid of a mantle heater, and then the reaction solution was processed in the same manner as in Example 1 to afford 6.4 g of scandium ethoxide as a white colored crystal. Yield 95.6%

Workup

  1. temperaturethe admixture in the flask was refluxed for 1 hour
  2. temperatureby heating with aid of a mantle heater

Sources & evidence

ORD record
ord-29f52e44bec548b7b6c20620b0073a9b
Source dataset
uspto-grants-1985_03
Patent number
US04507245

Reaction notes

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