trans-3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropylcarbonyl chloride → (6,7-Dihydro-5H-dibenzo[a,c]cyclohepten-4-yl)methyl 3-(2,2-Dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate

HRID 2164845Notes

Reaction equation

HRID 2164845 reaction equation
ClC(Cl)=C[C@H]1[C@H](C(Cl)=O)C1(C)C.[Cl:13][C:14]([Cl:40])=[CH:15][C@H:16]1[C@H:18]([C:19]([O:21][CH2:22][C:23]2[C:28]3[CH2:29][CH2:30][CH2:31][C:32]4[CH:37]=[CH:36][CH:35]=[CH:34][C:33]=4[C:27]=3[CH:26]=[CH:25][CH:24]=2)=[O:20])[C:17]1([CH3:39])[CH3:38]>>[Cl:13][C:14]([Cl:40])=[CH:15][CH:16]1[CH:18]([C:19]([O:21][CH2:22][C:23]2[C:28]3[CH2:29][CH2:30][CH2:31][C:32]4[CH:37]=[CH:36][CH:35]=[CH:34][C:33]=4[C:27]=3[CH:26]=[CH:25][CH:24]=2)=[O:20])[C:17]1([CH3:38])[CH3:39]

Participants

3

Reactant 2

HCID 11009700trans-3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropylcarbonyl chlorideHCID 86739267(6,7-dihydro-5H-dibenzo-[a,c]cyclohepten-4-yl)methyl trans-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate

Product 1

HCID 20403341(6,7-Dihydro-5H-dibenzo[a,c]cyclohepten-4-yl)methyl 3-(2,2-Dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate

Procedure

Similarly, but employing trans-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarbonyl chloride, (6,7-dihydro-5H-dibenzo[a,c]-cyclohepten-4-yl)methyl trans-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate was prepared.

Workup

  1. customwas prepared

Sources & evidence

ORD record
ord-39e92dfcd7374bb0b1235af5a408dce7
Source dataset
uspto-grants-1985_03
Patent number
US04507317

Reaction notes

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