Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 4-Chlorophenol | HCID 4684 | — |
| Reactant | Methyl 2-propen-1-yl carbonate | HCID 534788 | — |
| Catalyst | Triphenylphosphine | HCID 11776 | — |
| Catalyst | palladium(II) acetate | HCID 167845 | — |
| Product | p-Chlorophenyl allyl ether | HCID 257946 | 97.3% |
Reaction Steps
A mixture of 4-chlorophenol (1.28 g, 10 mmoles), allyl methyl carbonate (1.40 g, 12 mmoles), palladium acetate (11 mg, 0.05 mmole) and triphenyl phosphine (40 mg, 0.15 mmole) is heated at 70° C. for 2.5 hours. After removal of volatiles, the residue is subjected to bulb-to-bulb distillation (110° C., 4 mm Hg) to give 1.64 g, 97 percent of allyl 4-chlorophenyl ether.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04507492 |
|---|
| Source dataset | uspto-grants-1985_03 |
|---|
| ORD ID | ord-5db639bf8914462ab9e8c2ae1c805648 |
|---|
| Source note | uspto-grants-1985_03 |
|---|
