Benzoyl Peroxide → HCID 54546446, compound

HRID 2165105Notes

Reaction equation

HRID 2165105 reaction equation
[CH3:1][C:2]([CH3:13])([CH3:12])[C:3]#[C:4][C:5]1[CH:10]=[CH:9][C:8]([CH3:11])=[CH:7][CH:6]=1.[Br:14]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.CCCCCC>C(Cl)(Cl)(Cl)Cl>[CH3:1][C:2]([CH3:13])([CH3:12])[C:3]#[C:4][C:5]1[CH:6]=[CH:7][C:8]([CH2:11][Br:14])=[CH:9][CH:10]=1

Participants

6

Reactant 4

HCID 7187Benzoyl PeroxideHCID 8058HexaneHCID 67184N-bromobutanimideHCID 128614071-(3,3-Dimethylbut-1-yn-1-yl)-4-methylbenzene

Product 1

HCID 54546446HCID 54546446, compound

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

3.35 g of 4-(3,3-Dimethyl-1-butynyl)toluene, 3.47 g of N-bromosuccinimide and 100 mg of dibenzoylperoxide in 50 ml of carbon tetrachloride are refluxed for 8 hours. The mixture is filtered and the solvent removed under vacuum. The pure product is obtained as an oil following chromatography over silica gel using hexane as an eluant.

Workup

  1. filtrationThe mixture is filtered
  2. customthe solvent removed under vacuum
  3. customThe pure product is obtained as an oil

Sources & evidence

ORD record
ord-601813db736f4c16ade63c23595ec770
Source dataset
uspto-grants-1990_07
Patent number
US04939148

Reaction notes

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